First thing, make sure you have enough space on your hard drive for two copies of everything in your user account. To remove encryption, Filevault needs to copy all your files, and then deletes the encrypted part.
You could make another user account that doesn't use Filevault, transfer all your files and settings over, and then delete the old user account that does use Filevault. Not sure as i don't use Filevault.
Unless you are afraid of people getting at your computer, I would suggest putting sensitive items in encrypted disk images instead of using Filevault. Filevault is pretty buggy and slow as far as I know.