Correct me if I am wrong, since it's been a while, but I thought SATA and eSATA connectors are different to begin with.
😱
And like CanadaRAM pointed out, you need a PCIe card to hook up through eSATA connector a port-multiplier enclosure for SATA HDs and your Mac Pro. At least that's how mine is set up.
😉
Cheers.