VoLTE is not simply VoIP
Actually, Vizin, VoLTE is not simply VoIP. It requires support from the lower layers to improve voice performance and prioritise the voice traffic.
"plain" VoIP would not offer the same user experience and will be more prone to call drops, particularly at the cell edge, than VoLTE.
For the above reason, there is a difference between saying that a mobile supports VoIP and that the same mobile supports VoLTE. While all smart phones support VoIP not that many support VoLTE, at the moment.
It is very likely that mobile operators will not allow non-VoLTE terminals to make and receive calls on the mobile number provided by the operator, using VoIP over LTE. It would be difficult to guarrantee the quality of the call. Instead, they will probably use CSFB for these users. After all, over time there will be increasingly more spare capacity on 2G and 3G.
Having said that, a VoLTE phone could offer superior performance also for other VoIP services, not necessarily offered by the mobile operator. For that, however, the mobile operator should trust the QoS settings of the VoIP stream and offer the same QoS with VoLTE (QCI 1). In practice, however, I doubt mobile operators will accept to do that and there are many arguments why they wouldn't.