Does it mess with the ML recovery HD...?
I lost my recovery partition. Funny thing, when I went to Disk Utility to create a new partition for Mavericks, I used the handle to set it to about 64 GB. However, when it was done being created, it was basically half the size of my drive. I have a 256, so my original partition was down to like 130-ish and Mavericks took the rest.
I installed Mavericks fine, but then got tired of it, so I removed the second partition. However, now I lost my ML recovery partition. If I boot with ALT, I only have my one main boot volume. Not a biggie for me, as I'm doing a clean install when I get Mavericks. I also have a clone with the recovery partition still in-tact, as I just used it to do a disk repair.
So yeah, you may lose your ML recovery partition when setting up a dual-boot from the internal drive.