Yes, mine came fully charged also. That's normal. But it's recommended that you plug it in 8 hours before "using" the unit to allow the battery to condition/charge. I would imagine it's not that important, just a precaution. Also, you're pretty much doing the same thing (charging it for 8 hours), as long as there's not an event that causes the battery to kick in within that first 8 hours of you using it. So you should be fine. Do you have the supplied USB cable connecting the unit to your iMac? If not, then go ahead and plug it in, then go into System Preferences, then Energy Saver. Once there, click on the UPS tab at the top of the window, and you'll find you can set different automatic shut-down parameters. For example, your iMac will automatically save all open files and perform a normal shut down after, either running on battery power for a certain amount of time, or when the battery level reaches a certain percentage, or if it's been running on battery for a specificied number of minutes. Pretty cool stuff... Have fun with your iMac.
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I'm not sure about Amazon UK. I know that here in the states, those units are all sold/shipped by Amazon, rather than being through a vendor on Amazon. So after like $25, your order qualifies for free shipping. Also, here in the states mind you, you can sign up for the 30 day free trial of Amazon Prime, which gives you either Free Two-Day Shipping, or $3.99 per item Overnight Shipping. Maybe they offer something similar on Amazon UK? Give it a good look around. Also, be sure that you are finding a unit that is Sold and Shipped by Amazon themselves.
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Just be sure that it's a Pure Sine Wave unit. If it's not, then your local reseller might just not be familiar with the Active PFC Power Supply concept. I never heard of it until a couple years ago and a lot of people still don't know that new computers need Pure Sine Wave. Also, be careful, because some people or companies like to just make a sale. So even though they know a product isn't compatible, they know that chances are, you aren't going to have an incident which requires your UPS to kick into battery power until after the standard time limit for returns. Be careful.