I expect you could do this. Search on "diskutil coreStorage create" and you'll probably find instructions. I'm not sure if you have to use a specific brand/model of hard drive; in the past there were some issues with that in iMacs. I haven't seen anyone's write up of a replacement yet.
But I have to ask why? 128MB flash and 6TB HDD? Most folks doing anywhere near that kind of storage are gonna invest in external drives, especially since you've gotta back that up somehow. And again, RAID via Thunderbolt is plenty fast enough for lots of stuff. Look at the nMP to see how the heavy hitters manage this; it's not too different with the riMac.
I have nMP that I use for the heavy workload, its connected to an older TB Display and a pair of TB LaCie RAID external enclosures. I am not too impressed with the external HD though, the speed is OK (Black Magic ~300MBPS), but the latency is slow. The nMP has a 1TB SSD, so it's very fast and has very low latency, but I must work the massive images I deal with off on the external drives and deal with the lower performance.
The reason I am considering the riMac is the display..it's beautiful. With the Fusion drive I am hoping the latency would be low because of the SSD, and like the idea of the most recent data being available on the SSD without my intervention. The riMAc would have access to the external HD as well thru TB. I will probably do most of the serious image processing on the nMP, and the final detailed processing on the riMac.
I will also use the riMac for more mundane things like web browsing, viewing documents and PowerPoint presentations.
At the Apple store the riMac was just easier on my eyes that the TB display in general, text was really clear to my old eyes and images were just amazingly clear.
Anyway, just thinking out loud in a what if situation.
Cheers,
Mike