iTunes>Preferences>General, then Import Settings and under the Setting drop-down menu I suppose you could just change the bitrate to something smaller than you currently have. You should know though that doing this will greatly reduce the quality of the song. Then convert it to whatever file-type you have chosen at your new, smaller bitrate. I wouldn't really recommend this because it will probably make the song sound like crap. How big is the file and why do you need it smaller?