Dual Monitor LCD/CRT - How to get iTunes to Full Screen in the CRT monitor?

Seeking a way for itunes and other Mac applications to appear as Full screen in the secondary CRT TV Monitor. I hooked up the VGA - RCA Adapter, I am having difficulty finding documentation on using the second monitor.

Thanks

 

Clarification

I have a second monitor 800 X 600 resolution. Used as an Extended Monitor.

How can I Display applications Full Screen?
I do not want the titlebar on iTunes to burn into the screen and I can view the picture better by removing the borders. I want to maximize the real-estate.

Any documentation or any help on this?

[Solved] - Opening Video in iTunes. Right click and open in new window. Move the window to the small screen. Right Click and select full screen.