Thanks everyone! We tried the old Devolo Powerline stuff about 6 or 7 years ago and it worked great (at 2005 speed!), but only for 2 computers on separate wiring circuits. The newer extended parts of the basement and first story are on a newer wiring system, whereas the rest of the house has a lot of different circuits but they are essentially all connected. Putting one more computer on the Powerline system upstairs completely sucks the power from the other computer, and the same happens on the new circuit. This was with 14mb technology, so I assume that it would work a lot better on the 200mb stuff available today?
Maximum file transfer speed on the 2.4ghz network is around 2mb/s but this is rarely seen, more likely around 1.5mb/s. This is acceptable, as I am not used to anything faster, and my Internet speed is around 10mbit/s so is not held back by poor wifi. However the reason for the 5ghz experiment is due to the roll out of BT Fusion FTTC being imminent and essentially putting up my connection to a 50mbit and up service. Clearly on the current setup, the Broadband speed increases would not be really appreciated much as the network could not cope with it. I suppose the extra bandwidth would mean that each computer could have a larger share of the Internet connection (each stream HD) but that would be it.
So seeing as 5GHZ is out, is Powerline the only option?