There is a difference between Health and Charge.
Generally when plugged in, the charge will be in the high 90s, if not 100. It slowly goes down to 95 (when the battery reaches 100, the charger begins trickle charging) and then returns back to 100. So it won't stay at 100 despite being left plugged in.
Almost 3 year old thread.I can't explain why the battery doesn't say its charged beyond a certain percentage (i have the same problem, and I have 5 charge cycles on my MBP).