the items in the control center are chosen by an algorithm and you can't change it.
I'm not sure sensors will ever show up there, I've re-enabled home controls and none of mine do, or in any the screens the shows when you hit the favorites button. I think apple has taken the name "control center" literally, and only includes things you can control.
I have home in control center disabled normally, since you never know what you'll see there.
I do have home enabled in the lists at the bottom of the control center settings, that will give you a single button, that works similar to the favorites button on your screenshot.