ehh... (so many questions, so little time )
What brand of printer?
How is it connected?
Can you print, if you go through the normal print process (choose print from the File menu, not the icon that you showed)?
Can you print from some other app, maybe a test document in TextEdit?
Can you do a test print, probably through the printer's utility (if that exists) or a test print on the printer panel (on the printer itself)
Have you tried deleting, then reinstalling your printer?