I had a hunt around for a method to do this without any luck so just went ahead and tried the following and it worked. Sorry if it's a well known, documented method, but I thought I'd share.
Using High Sierra on my Mac Pro 5,1 I launched the Parallels installation of Windows 10 and attached a USB HDD, frustratingly the latest version of Parallels won't see drives installed in the drive bays. I then used the 'Backup & Restore' option to create a full system image on the external drive and then created a System Repair DVD.
I installed a new SSD in one of the drive bays using an Icydock and used Disk Utility to format it with FAT & MBR. Meanwhile I copied the Windows 10 system image from the external drive to an NTFS formatted HDD in one of the other SATA bays (this step may be unnecessary.)
I then removed all my other drives and rebooted from the Windows 10 System Repair DVD. Selected 'Advanced Options' and 'System Image Recovery' and selected the system image on the HDD.
It only took about 5 minutes to restore the image onto the new SSD and upon restart I was able to boot straight into the Windows 10 SSD.
There was a fair bit of activity initially as it updated drivers and devices and I had to reactivate it with the product key. I then installed the Apple software and all seems to be well. I moved the SSD onto an Apricorn Velocity PCI card and am now running it from there.
The only downside I've experienced so far is that the Image Recovery software sandwiched the Windows 10 partition between a system reserved partition and the recovery partition meaning I couldn't use disk manager to extend the OS partition. I used Diskpart to delete the recovery partition and was then able to extend the OS partition to the full size of the SSD.
Using High Sierra on my Mac Pro 5,1 I launched the Parallels installation of Windows 10 and attached a USB HDD, frustratingly the latest version of Parallels won't see drives installed in the drive bays. I then used the 'Backup & Restore' option to create a full system image on the external drive and then created a System Repair DVD.
I installed a new SSD in one of the drive bays using an Icydock and used Disk Utility to format it with FAT & MBR. Meanwhile I copied the Windows 10 system image from the external drive to an NTFS formatted HDD in one of the other SATA bays (this step may be unnecessary.)
I then removed all my other drives and rebooted from the Windows 10 System Repair DVD. Selected 'Advanced Options' and 'System Image Recovery' and selected the system image on the HDD.
It only took about 5 minutes to restore the image onto the new SSD and upon restart I was able to boot straight into the Windows 10 SSD.
There was a fair bit of activity initially as it updated drivers and devices and I had to reactivate it with the product key. I then installed the Apple software and all seems to be well. I moved the SSD onto an Apricorn Velocity PCI card and am now running it from there.
The only downside I've experienced so far is that the Image Recovery software sandwiched the Windows 10 partition between a system reserved partition and the recovery partition meaning I couldn't use disk manager to extend the OS partition. I used Diskpart to delete the recovery partition and was then able to extend the OS partition to the full size of the SSD.
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