OK, Toast won't do a sector copy, and it won't burn Red-book CD's, Jam will burn to the Red-book standard, and will operate from a disc image.
I'd say you have two choices here, image the disc using Disc Copy, drop the image into Jam and burn red book from there, this should preserve meta data and track relationships.
Otherwise, rip the disc into iTunes using the .aiff importer, then grop the files into Jam and re-build the disc to your spec.
The key is the Red-book burn and the preservation of meta data. iTunes also removes the annoying DRM codes, which will still be in place in an image.
If the intention is to preserve the quality of the original, then rip to iTunes and burn with Jam, if you're trying to circumvent anti-piracy features that's probably the easiest way, if you are genuinely tyring to reproduce an exact copy of the CD code, then you'll need a word-clock sychronisable source, a digital recorder with an AES/EBU digital input and some kind of audio editor (ProTools or Sonic Solutions will do).
...or you could just use diskcopy in toast, unless you're a genuine audiophile with a stack of very expensive hi-fi then you'll probably not hear the difference.