In addition to performance, there is one more thing to consider, depending how you use that additional storage.
Conventional SD cards like the one you propose, are simply bulk flash, with no write management. Typical SD cards are only provisioned for perhaps a thousand or so write cycles to each block of storage. In other words, the flash wears out if you use it too much.
SSDs on the other hand, have write management, and its internal controller will keep track of writes so that activity is spread automatically so no physical block is written too many times. This is transparent to the user as logically, the memory available is always available.
That said, my Macbook Air has a flush SD card installed that I use for occasional storage of files. Frequently used files that are updated are kept on the internal Air's SSD. Infrequent files that are mostly "read" are stored on the SD card[ ie music or reference documents.