I'm having a bad luck with electronics week except for my car alarm deciding to mysteriously work again after having been broken since October so I haven't really dealt with this since posting the OP.
Even with everything unplugged from the hub it was hot today when I took it off the shelf the drives sit on. The shelf is wood and the drives are warm, but not exceptionally so, and it's been pretty chilly here today. So, I don't know what the deal is. A powered USB 2 hub I have on the same shelf with two devices (a hard drive and a microphone) plugged in is cool to the touch.
In regards to the FireWire 400 DVD burner, is it not best that I have it plugged into the last device in the chain with all the other devices being 800?
I'm, frankly, a little nervous about trying to add any of the drives back to the FireWire hub; I had a USB 3.0 hub that malfunctioned and fried two hard drives in the process. What do you think? Try it again one drive at a time or just return it?
I really do need all 4 drives going at once, though, the DVD burner (and a Blue-Ray burner I haven't moved up here yet) can, of course, be plugged and unplugged as needed if I feel up for the minor inconvenience of doing so.