In APFS speak:
Your drive (Samsung...) has 2 visible partitions. Both partitions are formatted as APFS containers - Container disk7 and Container disk4.
Container disk7 has 4 volumes. These are sharing the total space allocated to the container. Flexible, but any of the 4 can fill the container - and you don't want that!
Container disk4 has 1 volume.
Here is what to do:
Think about what you will do if you make a mistake (or my instructions are wrong) and important data gets deleted.
In Terminal run the command diskutil list
. This will show you same as Disk Utility but with a bit more detail.
You are good to proceed so long as disk4 is after disk7 and there is nothing between them. If that is not true (or you are unsure), post the output and we (you, I and anyone else) can have a think about it.
If Untitled has anything of value, mount the volume and save the content somewhere else and dismount it. We are going to delete it!
Close any applications using the 4 volumes and temporarily disable your backup apps (Acronis, CCC and TM).
In Disk Utility (or Finder), dismount all the volumes (Acronis, etc). Possibly not necessary, but makes sure your disk is not being used.
In Disk Utility, select the drive (Samsung), and click the partition button near the top right.
This will show a pie with the two partitions. disk4 should be very small in the "5 to 12" position.
Select the disk4 container and click the minus button and yes to any prompts. This removes the partition. So do it carefully! Its share of the pie is very small, with makes selection a bit tricky.
You now have free space and can expand the disk7 partition to fill the whole drive. This may take a little while.
Mount the 4 volumes.
Make sure you can see their content in Finder
Re-enable your backup apps.
Done!