The original two sticks were already in the "normal" slots for one pair, but there's no requirement for specific arrangements, and your arrangement works fine.
All of your memory is recognized. You COULD boot to the diagnostic/hardware test, and run the extended test (Restart, while holding D).
The test will take quite a long time (maybe an hour with that much memory, IDK), but you probably don't need to run the test, unless you think you are having some problem with the hardware.
Are you having any actual problem?