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shift+command+3 takes full-screen shots
shift+command+4 gives you crosshairs and lets you take partials.

For the entire list, check out the handy Macrumors Guide

Edit: Oh, yeah, looks who's quick on the draw :)
 
To clarify, the "Apple" and "Command" keys are the same keys (it's technically called the Command key).

Some old-timers also will refer to it as "Flower" as in...

Flower+Shift+3
Apple+Shift+3
Command+Shift+3

...all the same thing...
 
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