USB-c SSD will make a fine external boot drive. You should get reads of about 430mbps and writes in the 350-375mbps range.
IF your fusion drive isn't "too full" yet, and IF all the contents will fit onto the SSD, the fastest way to accomplish this is:
1. Connect new SSD and use Disk Utility to format it to Mac format (either HFS+ or APFS)
2. Download CarbonCopyCloner from here:
http://www.bombich.com/download.html
(CCC is FREE to download and use for 30 days)
3. Launch CCC and clone the contents of the internal to the new SSD
4. When done, go to the startup disk pref pane and choose the SSD to be the boot drive
5. Reboot.
6. Done.
ONE MORE THING:
If you'd like more speed, you could get one of the these two solutions:
First solution:
Samsung X5 thunderbolt drive.
VERY VERY fast (will far outperform ANY fusion drive), but these are considerably more $$$$.
Second solution:
Get a "bare" nvme blade drive (MUST be "nvme")
Get a USB3.1 gen2 enclosure, such as this:
https://www.amazon.com/gp/product/B07N48N5GR/ref=ppx_yo_dt_b_asin_title_o00__o00_s00?ie=UTF8&psc=1
Put the drive into enclosure and set it up (same as above). Just click the button to open and "drop the drive inside".
This will give you read speeds up around the 850-900mbps range.
Not as fast as thunderbolt, but almost twice the speed of USB3.1 gen1.
And the cost is VERY reasonable for the additional speeds you'll get.