Some things are better suited to the terminal but many are best suited to the gui. For instance, to copy a folder containing thousands of files you can type right click it, pick copy, browse to the destination and click paste or you can type the following in terminal:
tar cf - * | ( cd /target; tar xfp -)
I don't know about you, but I prefer the gui for this.
I tend to use the terminal mostly for operating on "headless" linux servers. For instance, I have an old pc lying around inflicted with some flavor of windows. I pop in a Linux live distro, let it install, pick a static ip, then take my monitor and keyboard back to the machine I borrowed them from. Any future interaction with that machine is done remotely through a terminal.
There are times in OS X that I would rather use the terminal than the gui, but they are rare. If you are asking about "interesting terminal commands" to learn about doing things "better" in terminal than through the gui, I think you might be on the wrong track. If somebody is telling you the terminal is the "Manly Way" to use your Mac, they are a fossil throwback to the "Order of the Priesthood of the Sacred Machine" from some time back in the 1960's when only "Real Men" used computers and only spoke to them in ebcidic. People who claim the terminal is superior are victims of outmoded thinking. There is nothing superior about memorizing sed|awk|grep commands versus learning your way around system preferences. However, knowing your way around terminal gives you a lot more flexibility and promises to increase your knowledge of the inner workings of Unix in general and OS X in particular.
If you want to learn about Unix, the terminal provides an excellent opportunity to do so. Anything really dangerous will require sudo so as long as you avoid sudo during your learning process, go ahead and have fun. My favorite Unix book is from ORielly,
Unix in a Nutshell. It's arguably the only book you ever need. Those 700 page "bibles" contain a lot of fluff. The only down side for Linux users is "Nutshell" still talks about redhat package manager and doesn't cover some of the newer methods of keeping packages up to date. However, this is no big deal on OS X because SoftwareUpdate takes care of that for us.