3G refers to the third generation mobile data speeds, which can no longer be selectively disabled with the iPhone 4S. Whether it's 3G or 2G (GPRS and EDGE), you still pay the same amount for the data.
From the sound of it, you want to avoid an excessive data charge with your PAYG SIM. You can disable 'Cellular Data' in Settings -> General -> Network, which will stop the iPhone from sending or receiving data over the phone network.
That means the iPhone will only make/receive calls and texts. Is that what you're after? You'll still be able to use wi-fi for Internet access, of course.