click on the word document (or excel spreadsheet, or whatever), hit "apple-i", then under "open with" choose OpenOffice (isn't it NeoOffice for Macs?), and click "Change All..."
That works if I do it for each document, but is there a way to make it so that everytime I download a new Word or Excel file it automatically opens with OpenOffice instead of Microsoft Office.
That works if I do it for each document, but is there a way to make it so that everytime I download a new Word or Excel file it automatically opens with OpenOffice instead of Microsoft Office.