Apple never released drivers for Radeon RX 6700 XT. If you install Big Sur, you can use the RX-6800, 6800 XT, 6900 XT (or 6950 XT with some tinkering). If you install Monterey, you can additionally use the RX-6600, 6600 XT, or 6650 XT with some tinkering. See
this page for OCLP-compatible AMD GPUs.
You'll need
OpenCore Legacy Patcher to install Big Sur or later. Beware that RX 5xxx and 6xxx cards are only supported until Monterey on our older Mac Pros. The drivers break for us in Ventura and later due to lack of a CPU opcode (AVX2).
Side note - what model of SATA card are you using? It appears to be a PCIe x1 card, which is limited to 500 MB/s in a 4,1 or 5,1 Mac Pro. You'll saturate the card reading or writing to one drive. If you did a copy from one drive to the other, it would be limited to 250 MB/s or less, because of the x1 slot bottleneck.
There are x4 SATA 6G cards, but I wouldn't bother today. NVMe is so much faster, that high-performance SATA cards are close to a joke now. You'd need a 4-drive SATA RAID to approach the speed of a single M.2 drive.