I had ordered the 13-inch rMBP with 8GB RAM, and realized that was a mistake. I think you made a good call.
I wouldn't worry too much about it as the battery life seems to exceed Apple's 9 hour estimate, so you won't really be losing anything. And the i7 should not run hotter under a light workload, and the battery life difference should be minimal. But under medium/heavy workloads, yeah I'm sure the i7 gets hotter and burns through the battery more quickly.
From what I've read, there is a bigger difference between the 2.4 and 2.6 i5 processors. The i7 really only has the higher clock speed and an extra MB in caching. But you've already ordered, so I would test it out for a few days first. I think you're fine, though.