I did some testing 32GB memory module on MacPro5,1 in June 2019 (last month), but not with this exact configuration (W3690 and 3x32GB). https://forums.macrumors.com/thread...tibility-and-faq.2099103/page-9#post-27466087
According to my tests, my guess is:
W3690
* Windows 10 and Linux boots, but only recognizes only 2GB.
* OS X Yosemite 10.10 - unknown (but I guess that it boots and recognizes only 2GB like Windows).
* macOS 10.11 or later does not boot.
X5690 (tested)
* Windows 10 and Linux boots with 96GB 1333MHz.
* OS X Yosemite 10.10 boots with 96GB 1333MHz.
* macOS 10.11 or later does not boot.