Have either of you checked the battery status on the phone to see if maybe the phone watch app was syncing more than usual? It should be about 1%~ on any given day pending you don't go nuts and sync a bunch of crap. Additionally, For it to be a one off day, it's more likely to be an app than anything. with Watch OS2, many developers updated the apps, but didn't take full advantage of being able to use the watch exclusively. I use an app called Battle Camp, and it leaves a little monster on my watch ( like the old tamagachi's ), and it drains the battery because it's constantly looking for the phone to tell it if the monster is dead or alive.
Another issue may be the bluetooth signal, are you noticing the watch is on WIFI more than usual? When i'm at home i get better life as i am usually on wifi with the watch, and it works wonders. I work from home, so I probably have it a little better than most.
Any recent app installs, even if you think they may not be the culprit, it's important to know what you installed, maybe i can attempt to replicate