No.
Cellular data switching always uses your primary data (e)SIM up until the point that there is no RF signal (aka no service) for said carrier. Then it will attempt to switch to your secondary data SIM.
If all RF signals are low, because you are underground, in an elevator, building, etc. it just bounces back and forth leaving you with no usable service.
Seemed like a good idea, tried it for a week or two, ultimately turned it off. Might work better in a rural setting where one carrier is better than another.
But in my case where buildings are the issue (school gymnasiums mostly) it was completely useless.