45
edit:
In XP SP2:
If you use the calculator in "Standard" mode, it will evaluate 6 + 3 * 5 as 45.
When you switch to "Scientific", it will evaluate it as 21.
(order of precedence puts "*" higher than "+", and is evaluated first, same as if the expression were written in source code ("C", and others)).
Just for fun, did the same equation in OS-X, using Apple Calculator app:
Either Basic or Scientific - 21 is the result. I'll take consistent.
If you use RPN, the operators are evaluated in the order entered, with 45 as the result.
2nd Edit:
Tried same experiment with Palm T|X:
Same inconsistencies as Windows: Basic = 45. Advanced = 21.
Nice.......