Some notes about the CalDigit cards:
https://forums.macrumors.com/thread...sb-plus-3-1-not-working.2334922/post-30864312
The USB controller chip is limited to 4 Gbps ( < 500 MB/s) total (both ports added together) but that's faster than your non-NVMe USB 3.0 flash sticks.
The eSATA controller is also limited to 4 Gbps total.
Your MacPro3,1's four lane PCIe 1.0 slot is sufficient for the CalDigit FASTA-6GU3 since the 6GU3 has a four lane PCIe 2.0 switch with only two 1-lane PCIe controllers connected to it.
The Teamgroup appears to be limited to USB 2.0 speeds. Check the USB tab of System Information.app to make sure your USB devices are connecting with USB 3.0 speed (5 Gbp/s) instead of USB 2.0 speeds (480 Mb/s).
Your Agfaphoto USB sticks are on the low side of USB 3.0 speeds but not unexpected for cheap flash drives. Compare the speed with a different Mac?
You would have to interpret the
ioreg output or use
pciutils to ensure that the 6GU3 is connecting properly at PCIe 1.0 x4 and not PCIe 1.0 x1 since System Information.app does not show PCIe bridges.