Because the glass is chemically hardened (up to 20 times more than regular glass), it is naturally more brittle. Materials (especially metals and metallurgy) that are hardened have a higher surface tension than not-hardened materials. So when you drop it, that tension (which is higher) is going to be released in a crack.
As a counter, polycarbonate (Used in Nalgene bottles and high speed aircraft canopies) which has a very low surface tension is soft and nearly "shatterproof" because of it. On the other hand, because of the low surface tension, it is easily scratched.