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I'm pretty sure (sarcasm... absolutely, since I'm looking at the link in the store right now) you can buy a standalone copy of Office on Microsoft's web site... don't know why people keep insisting otherwise other than that they can't be bothered to actually look. As for *just* Excel, no, Microsoft stopped selling the apps individually a while back.
 
Did you try Ebay? You'd be surprised what you can find out there!

Edit: If you are looking for specific OLDER versions, this is a good way to go. Weirdos like me have been known to sell old versions of software / OSes.
 
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