Rewritten (should have read OP's post more clearly):
If you're going to use an SSD for an external booter, probably best to run it as a "straight SSD" without using fusion.
I've been doing it for three years now, works flawlessly.
If you don't have the Mini yet, best to get the 2014 model -with- the fusion drive already installed.
The "blade" SSD used is MUCH faster than any SATA SSD.