I recently bought and sold a dual 2GHz G5 logic board and processor set which would fit in a single 1.8GHz case - I checked thoroughly and it was a workable upgrade because the 1.8GHz had the right power supply.
HOWEVER: after the upgrade the board and processors need to undergo thermal calibration, or the fans don't operate appropriately. This is an authorized service center job, requiring special, not publicly available software.