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I doubt that will work, because the photos are not in the camera roll, so Photos wouldn't see them.

It's been a long time since I've relied a desktop photo program, but I thought Photos also synced albums. I can see albums I created on my iPad in the Photos app on my Macbook - but is that just because of iCloud Photos?
 
I had a ridiculously hard time trying to export photos from my friend's iPad to his windows work laptop. Ended up extracting them to my MacBook, then saving the files onto a thumb drive for him.
 
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