Homeopathy is placebo. Prayer is placebo. Going from 44.1k samples to 192k samples in audio is placebo.
I think you need a qualifier in the last one. I agree if you say, "for most people, with most music on most systems..."
I'm sure that there are people who with the right equipment and the right source material could tell the difference.
It's not really different than saying most people won't be able to tell the difference between a blu-ray movie and a 4K movie, but in certain circumstances you might be able to.