Not every computing task will necessarily benefit from parallelism. I'll run down your list and give a brief comment.
Safari, FireFox, Chrome --
The main place that browsers can do things in parallel is the fetching of web resources, such as HTML web pages, images, etc. and the rendering of those resources to the screen. That is, fetching things can use one core, while rendering the fetched things can use another core. Some decoding and rendering can also go in parallel. For example, if there are 5 images, each one can typically be decoded and rendered independently. There may be a bottleneck where a single core has to combine the layed-out text, images, etc. into a single window.
Also, if you have multiple tabs going at once, those can proceed in parallel.
Mail --
Not a lot can happen in parallel here, unless you have multiple mail accounts. Fetching mail is deliberately done sequentially (non parallel), so things don't break.
iChat --
How many chats do you have going at once? I can only manage one at a time, so I don't see much reason for parallelism here.
Preview --
At best, decoding multiple images at once could benefit from parallelism, but I can only look at one at a time.
Text editors and Word Processors --
I can only type in one document at a time, so not much use for parallelism.
MS Excel and the likes --
It depends. The dependencies between the cells and the formulas in each will decide how much can happen in parallel and how much needs to be sequential. Anything where the output of one cell is the input to another cell will probably need to be sequential.
music playing apps like iTunes --
I only listen to one audio stream at a time. If you were combining many many streams at once, there might be a case for parallelism, but unless it's in the dozens to hundreds of streams, I don't really see it being useful.
movies playing apps like VLC --
Decoding multiple streams at once could run in parallel, or fetching and decoding using different cores, but unless you're combining many streams, I don't see a major benefit to heavy parallelism.
FWIW, none of the above is specific to Apple Silicon. The same things apply to multi-core Intel Macs, and even multi-core PowerPC Macs.