1. Shoot at the highest (detail) picture setting as possible. ie. Maximum JPEG pixel count and, if possible, also in RAW picture format. That will also give you better control of the post processing you may need to do.
This is one thing i done since day one was turned it to RAW only, as i know at print that my printer wants a good tiff, i have also switched my camera to the ADOBE RGB colour space.
2. Tripod or monopod or soft bag to rest the camera on. I use a Jessops bean bag with a camera screw mount on it, a Manfrotto tripod as well as a Jobi Gorillapod-SLR Zoom! That last one is a bit of a mouthful but it is big enough to support an SLR camera with a medium sized zoom. ie. Anything from a 18-200mm down. I only carry the Gorillapod and bean bag or the tripod, but not all together. I'm not THAT fit!
I think i will be looking for a much better tripod, especially as the 2 lens i want are over a KG and my current tripod only supports 2kg and is already falling apart, but i did expect as much it was £20 and i only got it as a stop gap measure. 4 months = £5/month.
3. The lens is next most important. Good glass gives better results, especially at the levels of magnification you maybe looking to print out at. You use a nice Canon body so a matching Canon lens or a fast (slightly cheaper) Sigma lens should give that little extra edge in sharpness. Have a look at the websites such as cameralabs.com and look for the lens range you are interested in and see what they say. There's plenty other sites but that's just my personal favourite at the moment. Most modern lenses are brilliant in the middle compared to 20 years ago but it's as they get out to the edges that they lose the quality. You can help offset a bit of that by using different apertures but see what the tests and reviews say about the lens of your choice.
I plan on getting a Canon 14mm II 2.8L, a 24-70L and a 70-200 L 2.8 in the future, the first will be the 24-70L, the 14mm II will be next year for my trip to Japan, and the 70-200mm 2.8L IS will be for Otakon 2011. So this should cover my sharpness issues and range issues now that i have tried out different focal lengths. To add to this each lens will get a circular polarising filter as i found its effects so far to be terrific at helping pull out the details in vegetation and the sea(though not always desired for the sea).
4. Get the time of day right and the light will do the rest for you. Different times of the day give different light levels and that may affect your choice of focus and exposure points the camera is automatically looking at. Which leads me onto the last point.
This is one thing i have never thought about, usually i aim to go out when the sun is at its highest point as when it starts to set here it is very quick and buildings quickly look very dark and drab. As we progress into the summer i will be able to go out for longer and try out different levels of light.
5. If in doubt, go manual! That includes exposure and focus. You maybe able to zoom in on a point using the live view on your viewscreen at the rear and fine-tune your focusing using the manual focus ring on the lens.
Yep i am always in full manual mode though rare do i focus manually, i can't see very well on screens so i use the eye peace or plug it into my laptop for fine adjustments, however i think my problems may be the lens i have as my 50mm 1.8 is sharp edge to edge.
Exposure is also something i am working on, i do not quite understand some of the exposure settings yet but am starting to. One of the things my book taught was to only set one focus point which has made it much more efficient at auto focus though i worry this may cause issues.