How is that different from just leaving it at 100% plugged in?
It's due to the battery's state of charge.
Leaving a battery at 100% charge for long periods isn't ideal for the battery's longevity...
If you leave your battery plugged into the power socket for long periods, you're better off leaving the battery at a lower state of charge (ie 70% as per the default set in Aldente) and drawing all power from the power socket directly...
Does it matter? Well it depends on who you ask...
Some people don't care, as they'll sell/pass on/stop using the laptop well before they notice any ill effects...
Others do care. Typically these folks hang on to their gear for several years and wish to extend the usable life of the battery, or don't see the point in degrading their battery unnecessarily, or don't wish to pay for a battery replacement etc etc...
I use a similar app to AlDente for my windows laptops. Limit charge to around 50% when I'm plugged into the power socket for long periods. Works great, and has helped me extend the laptop's battery life for several more years...