The "PCI" that you see represented is kind of a "vestige" from back in the time when Macs actually came with "slots" into which you could plug expansion cards.
That time is "pretty much past" (we'll see if it changes when the new Mac Pro's come out).
If you wanted to use a PCI-based card today, I think you'd have to buy an "expansion chassis" which connects via thunderbolt, and go from there. Not even sure if such stuff still exists. And if it does, I'm going to -guess- that the options for what can be connected are pretty narrow.
What do you "have", that you need to "connect to"...?