I'm looking to design my own website.

[KnowNol]

I opened up iWeb and wasn't too impressed. Are there any other programs that will let me design a professional website?

 

[Forsaken]

Rapidweaver.

Crazy powerful, and if you search you'll find lots of themes for it. Good stuff.
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[angelwatt]

There's a Web Design & Development section here in the forums. Check it out and be sure to read through the stickies to see various software people recommend as well as a number of other helpful links.