There isn't any that explicitly tells you which interface is being used. The two network interfaces, however, will get different IP addresses if they are both active at the same time..
You might want to disable the WiFi and run a test purely on Ethernet to see what sort of speeds you get and then flip it around. With that baseline information, turn both on with the prioritization you want and re-test. Then try flipping the priority to see if it has any effect on the overall speed.
Ethernet, depending on the router, is either 100 Mbps or 1000 Mbps (most recent routers are the gigabit speed)..more expensive ones go to 10 gigabit. WiFI 802.11AC goes up to has a bunch of speeds depending on the bandwidth, but WiFi is very lossy, so you won't get anywhere near the theoretical max speeds..
Also when testing on either interface ensure that you test against the same site under the same circumstances..
Regards