Like Shake 'n' Bake says, I would have guessed the SD slot is probably on the same USB bus as the keyboard, trackpad and iSight, and if so it doesn't matter what speed the SD card is, it's not going to be any faster than USB2 can manage. If you wanted to boot off something external you'd be better off using a FW800 drive.
But it is cool you can boot off an SD slot if you need to, it'd be a handy thing to have an emergency bootable back up in such a small format.