There is no iPhone app to lock/unlock AW, nor AW app to unlock/unlock iPhone.
There is no API available from Apple on iOS or WatchOS to lock/unlock either.
You could unlock AW from iPhone as part of iOS/WatchOS function, not app, and it is because AW is extension of iPhone. Not other way around. Apple assume if you have access to master, iPhone, it will allow you to unlock slave, AW, if you turn on feature in iOS/WatchOS.