Thank you! Yea I enjoy shooting wildlife, birds, and nature scenery, so it seems I am in for a handful of trouble!
You will be in trouble only if you start worrying about ISO, shutter speed, and aperture. For the time being, use the instruction on the manual, or at least the one you posted:
100-200 Sunny
400-800 Cloudy
800+ Overcast is what I was told.
All depends on how fast your lens is, or if you are using flash. With your 100-400:
ISO 100 when sunny, and "maybe" 200 if sunny but taking a photo in the shade. In fact, you may even have to go up to 400 ISO to maintain a shutter speed high enough to prevent blurred images. When you look though the viewfinder, notice the shutter speed. If it's approaching a shutter speed of 100 and you are taking pictures of birds or any moving subject, you will have to open the lens to maximum (f/5.6), and also increase the ISO to bring the shutter speed at or higher than 100 for a stationary subject. For a bird in flight, you may want to use a shutter speed of 400 and higher.
On a cloudy day, you can try 400 ISO first, and then 800 if it needs to be higher (again, if the subject is moving you want high shutter speeds).
Like others have said, don't be afraid experiment with your camera. But for the time being, use the options you mentioned. The key is to crank the ISO up, just as much as needed to avoid blurry subjects, and you should be able to tell when you are looking though the viewfinder (notice the shutter speed).
I would also advise to buy one of the David Bush books specifically written for your T2i. It will save you a lot of time learning how to use it.