Small computer on a large adapter is of course not a problem.
But I've measured my MPB (17", admittedly) drawing over 70W when it wasn't even charging the battery. If there's a limiter in the MB 65W adapter, then it's ok--if the MPB tries to draw too much, it'll just cut out. If not, it could very well overheat and damage itself.
I, personally, wouldn't try it. Even the proper 85W adapter gets darn toasty at those loads.