A lithium-ion battery (sometimes Li-ion battery or LIB) is a type of rechargeable battery in which lithium ions move from the negative electrode to the positive electrode during discharge, and reversely when charging. During discharge the negative electrode is the anode where oxidation takes place and during charge it turns into the cathode where reduction takes place. This functional meaning of the words anode and cathode is however widely ignored in the slang of battery-specialists: "anode" means negative electrode and "cathode" means positive electrode. For consistency, the latter practice is followed in this article. Different types of lithium-ion batteries use different chemistry and have different performance, cost, and safety characteristics. Unlike lithium primary batteries (which are disposable batteries), lithium-ion cells use an intercalated lithium compound as the electrode material instead of metallic lithium.
Disadvantages:
A disadvantage of lithium-ion cells is their poor cycle life: upon every charge or recharge, deposits form inside the electrolyte that inhibit lithium ion transport. Over time, the capacity of the cell diminishes. The increase in internal resistance affects the cell's ability to deliver current. This problem is more pronounced in high-current applications. The increasing capacity hit means that a full charge in an older battery will not last as long as one in a new battery (although the charging time required decreases proportionally, as well).
Also, high charge levels and elevated temperatures (whether resulting from charging or being ambient) hasten permanent capacity loss for lithium-ion batteries. The heat generated during a charge cycle is caused by the traditional carbon anode, which has been replaced with lithium titanate. Lithium titanate has been experimentally shown to drastically reduce the degenerative effects associated with charging, including expansion and other factors
At a 100% charge level, a typical Li-ion laptop battery that is full most of the time at 25 °C or 77 °F will irreversibly lose approximately 20% capacity per year. However, a battery in a poorly ventilated laptop may be subject to prolonged exposure to higher temperatures, which will shorten its life. Different storage temperatures produce different loss results: 6% loss at 0 °C (32 °F), 20% at 25 °C (77 °F), and 35% at 40 °C (104 °F). When stored at 40%–60% charge level, the capacity loss is reduced to 2%, 4%, 15% at 0, 25 and 40 degrees Celsius respectively.
Internal resistance
The internal resistance of lithium-ion batteries is high compared to other rechargeable chemistries such as nickel-metal hydride and nickel-cadmium. Internal resistance increases with both cycling and chronological age. Rising internal resistance causes the voltage at the terminals to drop under load, which reduces the maximum current that can be drawn. Eventually the internal resistance reaches a point at which the battery can no longer operate the equipment for an adequate period.
Li-ion batteries are not as durable as nickel metal hydride or nickel-cadmium designs, and can be extremely dangerous if mistreated. They may suffer thermal runaway and cell rupture if overheated or if charged to an excessively high voltage. In extreme cases, these effects may be described as "explosive." Furthermore, they may be irreversibly damaged if discharged below a certain voltage. To reduce these risks, lithium-ion batteries generally contain a small circuit that shuts down the battery when it is discharged below about 3 V or charged above about 4.2 V. In normal use, the battery is therefore prevented from being deeply discharged. When stored for long periods, however, the small current drawn by the protection circuitry may drain the battery below the protection circuit's lower limit, in which case normal chargers are unable to recharge the battery. More sophisticated battery analyzers can recharge deeply discharged cells by slow-charging them to reactivate the safety circuit and allow the battery to accept charge again.
Guidelines for prolonging lithium-ion battery life
* Lithium-ion batteries should never be depleted below their minimum voltage (2.4 to 2.8 V/cell, depending on chemistry). If a lithium-ion battery is stored with too low a charge, there is a risk that the charge will drop below the low-voltage threshold, resulting in an unrecoverable dead battery. Usually this does not instantly damage the battery itself but a charger or device which uses that battery will refuse to charge a dead battery. The battery appears to be dead or not existent because the protection circuit disables further discharging and there is zero voltage on the battery terminals.
* Lithium-ion batteries should be kept cool. They may be stored in a refrigerator.
* Lithium-ion batteries degrade much faster if stored in high-temperature areas.
Restrictions on transportation
As of January 2008, the United States Department of Transportation issued a new rule that permits passengers on board commercial aircraft to carry lithium batteries in their checked baggage if the batteries are installed in a device. Types of batteries affected by this rule are those containing lithium, including Li-ion, lithium polymer, and lithium cobalt oxide chemistries. Lithium-ion batteries containing more than 25 grams equivalent lithium content (ELC) are exempt from the rule and are forbidden in air travel. This restriction greatly reduces the chances of the batteries short-circuiting and causing a fire.
Additionally, a limited number of replacement batteries may be carried on as luggage. Such batteries must be sealed in their original protective packaging or in individual containers or plastic bags.
On 2009 fall, at least some postal administrations restricted air shipping (including EMS) of lithium batteries, lithium-ion batteries and products containing these (e.g. laptops, cell phones etc). Among these countries are Hong Kong, and Japan.