Battery Percentage is the new "XX Minutes Remaining".
When you're downloading a file or installing an update, you'll notice that you get a progress bar, and sometimes you'll get some text: "XX Minutes Remaining". You'll also notice that the "XX" tends to bounce around. How could a task have "12 minutes remaining", and then a couple of minutes later show "21 minutes remaining", you'll ask yourself.
Same thing with battery percentage.
The physical measurement of battery percentage is somewhat imprecise. Also, lots of external things can happen: the battery gets warmer or colder; the ambient temperature gets warmer or colder, the voltage spikes or down; the voltage at the plug ramps up or down. Mebbe cosmic rays, who knows?
You can obsess or not obsess over battery percentage, IDGAF. I, myself, have achieved infinite bliss by not worrying about things. Be like me.