When you increase the complexity, you increase the risk of things going pear shaped.
Over the years, I've seen way to many innovative and quirky set-ups like this go exactly that way...pear-shaped.
KISS - Keep it simple. Backups are too important to be messed with. One drive for backup and one drive for your bootable clone.(And some posters here, quiet rightly tell you, that even one backup is not good enough and you should be using a second backup medium like online backup).