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You can try, depends on how busy it is and the number of reps available.

There was a member who posted he picked up earlier than the time slot.
 
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Yes I did...I had a 5-5:15 appointment time and I picked up my phone at 8AM. I dont know if all Apple Stores allow it but mine did with no problems at all.
 
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Desert Titanium 16 pro max available today right now (also in black and natural) at my local Apple Store in Northern VA. Unlocked any carrier. People didn’t need to preorder those
 
In my experience, they don’t let you pick up earlier than your allotted time. At least in nyc. You can pick up anytime after tho.
 
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